dichloro(N-p-tolylpyridine-2-aldimine)copper(II) | 201735-97-9

• 英文名称: dichloro(N-p-tolylpyridine-2-aldimine)copper(II)
• CAS: 201735-97-9
• 化学式: C₁₃H₁₂Cl₂CuN₂
• 分子量: 330.704
• InChiKey: DQMXGJDDQMNQKB-RJQKUYQSSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis-(2-p-tolylpyridinecarboxaldimine)silver(I)perchlorate 、 dichloro(N-p-tolylpyridine-2-aldimine)copper(II) 以 甲醇 为溶剂， 以76%的产率得到tris(N-p-tolylpyridine-2-aldimine)copper(II) perchlorate
  参考文献：
  名称：

  Silver(I) Assisted Metal Exchange Reaction. A Generalized Synthesis of Tris-Chelated Copper(II) Complexes of Neutral N,N-Donors

  摘要：

  A novel and direct synthetic route for the syntheses of hexacoordinated cupric complexes involving bidentate N,N-donor ligands has been elaborated. This synthetic strategy has been successfully applied for the preparation of mixed-ligand tris(chelates).[GRAPHICS]pathways and that reaction from the lowest lying LF triplet level occurs with a greatly reduced photoefficiency. W(CO)(4)(en) h nu-->CH3CN W(CO)(3)(en)(CH3CN) + CO

  DOI：

  10.1021/ic970819m
• 作为产物：
  描述：

  N-(pyrid-2-ylmethylene)-p-tolylamine 、 copper(II) choride dihydrate 以 乙腈 为溶剂， 以84%的产率得到dichloro(N-p-tolylpyridine-2-aldimine)copper(II)
  参考文献：
  名称：

  Silver(I) Assisted Metal Exchange Reaction. A Generalized Synthesis of Tris-Chelated Copper(II) Complexes of Neutral N,N-Donors

  摘要：

  A novel and direct synthetic route for the syntheses of hexacoordinated cupric complexes involving bidentate N,N-donor ligands has been elaborated. This synthetic strategy has been successfully applied for the preparation of mixed-ligand tris(chelates).[GRAPHICS]pathways and that reaction from the lowest lying LF triplet level occurs with a greatly reduced photoefficiency. W(CO)(4)(en) h nu-->CH3CN W(CO)(3)(en)(CH3CN) + CO

  DOI：

  10.1021/ic970819m