(((C6H5)2P)2C20H12)Ni(cod) | 958292-97-2

• 英文名称: (((C6H5)2P)2C20H12)Ni(cod)
• CAS: 958292-97-2
• 化学式: C₅₂H₄₄NiP₂
• 分子量: 789.559
• InChiKey: GNQNGNITWKIVQO-LKZSQVSZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,8-diphenylphosphinotriptycene 、 bis(1,5-cyclooctadiene)nickel (0) 以 not given 为溶剂， 生成 (((C6H5)2P)2C20H12)Ni(cod)
  参考文献：
  名称：

  Highly Selective Hydrocyanation of Butadiene toward 3-Pentenenitrile

  摘要：

  A triptycene-based diphosphine ligand was synthesized in good yield following a new route. The corresponding Pt(II)- and Ni(0)complexes were characterized. In butadiene hydrocyanation the tript-PPh2Ni(cod) catalyst leads to exceptionally high selectivities for the linear product 3-pentenenitrile, combining high activity for both hydrocyanation and isomerization. This one-step procedure could be the key toward process intensification.

  DOI：

  10.1021/ja074922e