| 860453-14-1

• CAS: 860453-14-1
• 化学式: C₁₂Fe₄NO₁₂*C₃₆H₃₀AuP₂
• 分子量: 1295.07
• InChiKey: DQCHBFSMNSPAAU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Et₄N][Fe₄N(CO)₁₂] 、 triphenylphosphine gold 3-hydroxy-3-methyl-1-pentynylide 以 二氯甲烷 为溶剂， 以62.2%的产率得到
  参考文献：
  名称：

  Use of phosphine gold acetylides [(R3P)AuCCR] to form phosphine gold derivatives of tetra-iron and penta-iron clusters

  摘要：

  Five new gold acetylides, [AuC equivalent to CR], with hydroxyl or amino functions in the organic radical R have been prepared. From these, nine phosphine complexes [(R3P)AuC equivalent to CR] with R = Ph or Cy were synthesised. Reactions between the phosphine gold acetylides [(Ph3P)AuC equivalent to CC(Me)(OH)Et] or [(Cy3P)AuC equivalent to CC(Me)(OH)Et] and the iron carbonyl cluster [Et4N][Fe4N(CO)(12)] gave both neutral [(R3P)AuFe4N(CO)(12)] and ionic compounds [(R3P)(2)Au][Fe4N(CO)(12)]. Reaction with the penta-iron cluster [Et4N][Fe5N(CO)(14)] afforded [(R3P)(2)Au][Fe5N(CO)(14)], [(R3P)(2)Au][Fe4N(CO)(12)] and [(R3P)AuFe4N(CO)(12)]. The gold-iron clusters were characterised with spectroscopic methods (IR, NMR and Mossbauer) and in the case Of [(Cy3P)AuFe4N(CO)(12)] a single-crystal X-ray analysis. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.02.045