| 663154-04-9

• CAS: 663154-04-9
• 化学式: C₅₆H₄₉ClP₃Pt₂S₂
• 分子量: 1304.67
• InChiKey: DIZHIKBHDRBSPC-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cis-dichlorobis(triphenylphosphine)platinum(II) 以 甲醇 、 苯 为溶剂， 生成 [Pt2(μ-SCH2CH2S)(triphenylphosphine)4](2+) 、
  参考文献：
  名称：

  Electrospray mass spectrometric investigation of the reactivity of the sulfide centers in [Pt2(μ-S)2(PPh3)4] towards organic dihalides and the catalytic potential of this complex in the syntheses of organosulfur materials

  摘要：

  Activity Of [Pt-2(mu-S)(2)(PPh3)(4)] (1) towards 1,4-dichlorobutane, 1,2-dichloroethane, alpha-alpha'-dichloro-o-xylene and alpha-alpha'-dichloro-m-xylene and the catalytic role of 1 in the syntheses of organosulfur materials was studied by in situ electrospray mass spectroscopy (ESMS). An intermediate, [Pt-2(mu-SC2H4S)(PPh3)(4)][PF6](2) (6) was isolated and characterized by single-crystal X-ray crystallographic diffractometry. In all reactions studied, the {Pt2S2} core is preserved, except for those involving excess NaBH4. Treatment of 6 with excess NaBH4 leads to the formation of mononuclear complex [Pt(eta-S2C4H8)(PPh3)]. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(03)00308-x