[Cd(bis(3-(4-pyridyl)-2,4-pentanedionato)beryllium)2Cl2]*H2O | 858861-94-6

• 英文名称: [Cd(bis(3-(4-pyridyl)-2,4-pentanedionato)beryllium)2Cl2]*H2O
• CAS: 858861-94-6
• 化学式: C₄₀H₄₀Be₂CdCl₂N₄O₈*H₂O
• 分子量: 924.135
• InChiKey: XECYLKOUFXDISA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(3-(4-pyridyl)-2,4-pentanedionato)beryllium - water - methanol (2/1/1) 、 cadmium(II) chloride 以 甲醇 、 氯仿 、 水 为溶剂， 以20%的产率得到[Cd(bis(3-(4-pyridyl)-2,4-pentanedionato)beryllium)2Cl2]*H2O
  参考文献：
  名称：

  Heterobimetallic Cd(Zn)/Be coordination polymers involving pyridyl functionalized beryllium diketonates

  摘要：

  Pyridyl functionalized molecular diketonates (bis-[3-(4-pyridyl)-2,4-pentanedione]beryllium, BeL21,; bis-[3-(4-pyridylethylene)-2,4-pentanedione]beryllium, BeL22; bis-[1-(4-pyridyl)-1, 3-butanedione] beryllium, BeL23) were employed for modular construction of Cd(Zn)/Be alternating coordination polymers. X-ray structure analyses revealed a structural diversity of the heterobimetallic compounds, such as H-bonded molecular complex [Cd{BeL21}(2)Cl-2] center dot H2O; coordination/hydrogen bonded double-chain polymer [Cd{BeL21} (MeOH)(NO3)(2)]center dot CHCl3 center dot 0.5MeOH; 2D structure of the linear [Cd{BeL21}](infinity) chains connected by NCS- bridges; interpenetration of 3D octahedral frameworks formed by hydrogen bonding between linear [M(H2O)(4){BeL21}](infinity) chains and ClO4- counteranions in [M(H2O)(4){BcL(2)(1)}](ClO4)(2)(M=Zn, Cd); interpenetrated bilayer polymer [Cd-2{BeL32}(3)(MeOH)(NO3)(3)](NO3)center dot 4.5MeOH also involving nitrate bridges; 1D chain of heterobimetallic squares housing guest molecules [Cd{BeL32}(2)I-2 center dot 2CHCl(3). (C) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.02.023