| 1308271-04-6

• CAS: 1308271-04-6
• 化学式: C₅₄H₄₉BN₂O₈
• 分子量: 864.803
• InChiKey: VMCHVCSBNRCAOQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 potassium carbonate 、 sodium hydroxide 作用下， 以 乙醇 、 乙腈 为溶剂， 反应 13.0h， 生成
  参考文献：
  名称：

  Water-Soluble Phosphonate-Substituted BODIPY Derivatives with Tunable Emission Channels

  摘要：

  Water-soluble BODIPY dyes have been readily obtained by introduction of phosphonate fragments either on the boron for the green and yellow emitting dyes or on the side chain for the red emitting dyes. Hydrolysis of the phosphonate is realized at the end of the reaction sequence and allows isolation of the targets by precipitation. All these novel dyes are soluble and fluorescent in water with quantum yields in the 23-59% range and emission wavelength spanning from 667 to 509 nm.

  DOI：

  10.1021/ol200969r
• 作为产物：
  描述：

  在 bis-triphenylphosphine-palladium(II) chloride 、 三乙胺 、 potassium hydroxide 作用下， 以 甲醇 、 苯 为溶剂， 70.0 ℃ 、101.33 kPa 条件下， 反应 12.0h， 生成
  参考文献：
  名称：

  Water-Soluble Phosphonate-Substituted BODIPY Derivatives with Tunable Emission Channels

  摘要：

  Water-soluble BODIPY dyes have been readily obtained by introduction of phosphonate fragments either on the boron for the green and yellow emitting dyes or on the side chain for the red emitting dyes. Hydrolysis of the phosphonate is realized at the end of the reaction sequence and allows isolation of the targets by precipitation. All these novel dyes are soluble and fluorescent in water with quantum yields in the 23-59% range and emission wavelength spanning from 667 to 509 nm.

  DOI：

  10.1021/ol200969r