dichloro[η(10)-2,4-cyclopentadien-1-ylidene(1-diphenylmethylene)(2,7-diphenyl-9H-fluoren-9-ylidene)]hafnium | 182480-33-7

• 英文名称: dichloro[η(10)-2,4-cyclopentadien-1-ylidene(1-diphenylmethylene)(2,7-diphenyl-9H-fluoren-9-ylidene)]hafnium
• 英文别名: dichloro[η(10)-2,4-cyclopentadien-1-yliden(1-diphenylmethylen)(2,7-diphenyl-9H-fluoren-9-yliden)]hafnium
• CAS: 182480-33-7
• 化学式: C₄₃H₃₀Cl₂Hf
• 分子量: 796.107
• InChiKey: HEOVQBNGLWIMPR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1-(2,4-cyclopentadien-1-yl)-1-(2,7-diphenylfluorenyl)-1,1-diphenylmethane 、 氯化铪 在 正丁基锂 、 lithium 作用下， 以 乙醚 、 正己烷 、 甲苯 为溶剂， 以67 %的产率得到dichloro[η(10)-2,4-cyclopentadien-1-ylidene(1-diphenylmethylene)(2,7-diphenyl-9H-fluoren-9-ylidene)]hafnium
  参考文献：
  名称：

  NOVEL TRANSITION METAL COMPOUND, TRANSITION METAL CATALYST COMPOSITION CONTAINING THE SAME, AND METHOD FOR PRODUCING COPOLYMER OF ETHYLENE AND a-OLEFIN USING THE SAME

  摘要：

  The present disclosure relates to a novel transition metal compound, a transition metal catalyst composition having high catalytic activity for producing a copolymer of ethylene and α-olefin containing the same, a method for producing a copolymer of ethylene and α-olefin using the same, and a copolymer of ethylene and α-olefin produced using the same.

  公开号：

  US20240010665A1

文献信息

• Syndiospezifische polymerisation von propylen: 2- und 2,7-substituierte metallocenkomplex des typs (C13H8−nRnCR′2C5H4)MCl2 (n = 1,2; R  alkoxy, alkyl, aryl, hal; R′  Me, Ph; M  Zr, Hf)
  作者：Helmut G. Alt、Roland Zenk

  DOI：10.1016/0022-328x(95)06045-x

  日期：1996.9

  Seventeen new catalyst. precursors for the syndiospecific polymerization of propylene are presented. The new metallocene complexes are substituted in the positions 2 and 7 of the fluorenlidene fragment by MeO-, halogen-, alkyl- and aryl groups. The focus is directed on effective new synthetic routes to substituted fluorenes and the preparation of Be catalyst precursors. In addition first polymerization results are reported.