(p-chloroanilide)(5,6-diphenyl-3-(2-pyrazinyl)-1,2,4-triazine)trichlororhenium(VI) | 1044741-13-0

• 英文名称: (p-chloroanilide)(5,6-diphenyl-3-(2-pyrazinyl)-1,2,4-triazine)trichlororhenium(VI)
• CAS: 1044741-13-0
• 化学式: C₂₅H₁₇Cl₄N₆Re
• 分子量: 729.469
• InChiKey: NOYKCBURLZUBGL-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 拓扑面积：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (p-chloroanilide)(5,6-diphenyl-3-(2-pyrazinyl)-1,2,4-triazine)trichlororhenium(V) 以 乙腈 为溶剂， 生成 (p-chloroanilide)(5,6-diphenyl-3-(2-pyrazinyl)-1,2,4-triazine)trichlororhenium(VI)
  参考文献：
  名称：

  Synthesis and characterization of new imidorhenium(V) and imidorhenium(VI) complexes of pyridyltriazines and pyrazinyltriazine with halide coligands including rare iodide

  摘要：

  The blue colored imido complexes [Re(NC6H4Cl)X-3(L)] have been synthesized by three methods: (i) reaction of [(ReOX3)-O-V(L)] with p-ClC6H4NH2, (ii) reaction of [Re-III(OPPh3)X-3(L)] with p-ClC6H4NH2 and (iii) reaction of [(ReOX3)-O-V(PPh3)(2)] with L followed by the addition of p-ClC6H4NH2 in boiling toluene. Here, X = Cl, Br, I and L are 5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine (L-2) and its dimethyl (L-1) and pyrazinyl (L-3) analogues. The [Re(NC6H4Cl) Cl-3(L-1)] (1a), [Re(NC6H4Cl)Cl-3(L-2)] (1b), [Re(NC6H4Cl) Br-3(L-2)] (1c), [Re(NC6H4Cl)I-3(L-2)] (1d), [Re(NC6H4Cl)Cl-3(L-3)] (1e), [Re(NC6H4Cl)Br-3(L-3)] (1f), [Re(NC6H4Cl)I-3(L-3)] (1g), complexes have been characterized electrochemically and spectroscopically. The X-ray structures of [Re(NC6H4Cl)Cl-3(L-2)] and [Re(NC6H4Cl)I-3(L-3)] reveal that the ReCl3 fragment is meridionally disposed and that the L ligand is N,N-coordinated such that the pyridine/pyrazine nitrogen lies trans to the imide nitrogen. The feasibility of generating the rhenium(VI) congener of the imidorhenium(V) complex is also examined with the help of six-line EPR spectra at room temperature. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.02.001