2,3,4,5,6,7,8,9,10,11,12-undecamethylcarba-closo-dodecaborate | 958632-43-4

• 英文名称: 2,3,4,5,6,7,8,9,10,11,12-undecamethylcarba-closo-dodecaborate
• 英文别名: [(2-12)-Me11CB11H]；1-H-closo-CB11Me11
• CAS: 958632-43-4
• 化学式: C₁₂H₃₄B₁₁
• 分子量: 297.323
• InChiKey: GEXSSGLIYRXPIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2,3,4,5,6,7,8,9,10,11,12-undecamethylcarba-closo-dodecaborate 以 二氯甲烷 、 二氯甲烷-D2 为溶剂， 生成 trans-[PtMe(iPr3P)2(THF)][1-H-closo-CB11Me11]
  参考文献：
  名称：

  [PtMe(ⁱPr₃P)₂]⁺: a Pt(ii) complex with an agostic interaction that undergoes C–H activation

  摘要：

  T型Pt(II)杂化物[PtMe(iPr3P)2][1-H-closo-CB11Me11]在卤素相互作用的稳定下，经过酸催化的分子内C–H活化，在THF的存在下生成环金属化的[Pt(THF)(iPr3P)(iPr2PCHMeCH2)][1-H-closo-CB11Me11]。

  DOI：

  10.1039/b410846a

文献信息

• B–C activation in highly alkylated carborane monoanions partnered with cationic transition metal fragments: observations and comments
  作者：Michael J. Ingleson、Gabriele Kociok-Köhn、Andrew S. Weller

  DOI：10.1016/j.ica.2004.09.048

  日期：2005.3

  Cage decomposition products of the highly methylated, weakly coordinating, carborane anion [1-H-closo-CB11Me11](-) are described. These arise both from well-defined metal complexes of [1-H-closo-CB11Me11](-) that already have BCH3 (...) [M] interactions and from attempts to partner this anion with other metal centres. In all cases the decomposition results in B-CH3 bond cleavage and solvent activation to form products with B-aryl or B-Cl vertices. (c) 2004 Published by Elsevier B.V.