[((CH3)4C5(CH2)3NH2)Rh(N,N'-(1,2-phenylene)bis(trifluoromethanesulfonamide)(-2H))] | 1224452-68-9

• 英文名称: [((CH3)4C5(CH2)3NH2)Rh(N,N'-(1,2-phenylene)bis(trifluoromethanesulfonamide)(-2H))]
• CAS: 1224452-68-9
• 化学式: C₂₀H₂₄F₆N₃O₄RhS₂
• 分子量: 651.456
• InChiKey: PVYHJTQBKDTEPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Cl2Rh{η5:η1-C5(CH3)4(CH2)3NH2}] 、 N,N'-(1,2-phenylene)bis(1,1,1-trifluoromethanesulfonamide) 在 KOC(CH₃)3 作用下， 以 not given 为溶剂， 生成 [((CH3)4C5(CH2)3NH2)Rh(N,N'-(1,2-phenylene)bis(trifluoromethanesulfonamide)(-2H))]
  参考文献：
  名称：

  Synthesis and Structure of Protic Amine Tethered Rhodium(III) Peralkylcyclopentadienyl Complexes

  摘要：

  A series of mononuclear tethered complexes, Rh(III)-(eta(5):eta(1)-Cp'-NHR), in which the eta(5)-peralkylcyclopentadienyl group and the ligated protic amine group are connected by suitable carbon chains, were newly prepared and structurally characterized. Their catalytic performance in the reductive amination of carbonyl compounds was significantly influenced by the chain length of the tether, which possibly plays a key role in determining the reaction course.

  DOI：

  10.1021/om100151m