1-chloro-2-phenyl-1-(pyridin-1-ium-1-yl)ethan-1-ide | 122540-70-9

• 英文名称: 1-chloro-2-phenyl-1-(pyridin-1-ium-1-yl)ethan-1-ide
• CAS: 122540-70-9
• 化学式: C₁₃H₁₂ClN
• 分子量: 217.698
• InChiKey: JUCFJZGENKPABH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  1-chloro-2-phenyl-1-(pyridin-1-ium-1-yl)ethan-1-ide 在 吡啶 作用下， 以 异辛烷 为溶剂， 生成 氯乙烯基苯
  参考文献：
  名称：

  Liu, Michael T. H.; Bonneau, Roland, Journal of the American Chemical Society, 1990, vol. 112, # 10, p. 3915 - 3919

  摘要：

  DOI：
• 作为产物：
  描述：

  吡啶 、 Benzylchlorocarbene 以 异辛烷 为溶剂， 生成 1-chloro-2-phenyl-1-(pyridin-1-ium-1-yl)ethan-1-ide
  参考文献：
  名称：

  Liu, Michael T. H.; Bonneau, Roland, Journal of the American Chemical Society, 1990, vol. 112, # 10, p. 3915 - 3919

  摘要：

  DOI：

文献信息

• Laser Flash Photolysis Study of Alkylhalocarbenes Generated from Non-Nitrogenous Precursors
  作者：Marc Robert、Igor Likhotvorik、Matthew S. Platz、Sarah C. Abbot、Mary M. Kirchhoff, and、Richard Johnson

  DOI：10.1021/jp972464y

  日期：1998.2.1

  Previously we have studied the photochemistry of alkylchlorodiazirines using laser flash photolysis methods and the pyridine ylide technique (White et al. J. Org. Chem. 1992, 17, 2841). The yield of trappable carbene was found to be a sensitive function of the alkylcarbene structure. This was attributed to ring opening of the diazirine to form a biradical which could suffer rearrangement, in addition to fragmentation to a carbene. It was also possible to explain the data in terms of a carbene-pyridine complex which can either rearrange or collapse to an ylide. In this work, alkylchlorocarbenes are generated from phenanthridenes. The results do not rule out the intermediacy of a carbene-pyridine complex; however, if this species is formed, it does not rearrange to chloroalkene in competition with collapse to form an ylide. This study reduces the urgency with which to postulate carbene-olefin complexes (Tomioka et al. J. Am. Chem. Soc. 1984, 106, 454).
• Measurement of the absolute rate of 1,2-hydrogen migration in benzylchlorocarbene
  作者：James E. Jackson、N. Soundararajan、Walter White、Michael T. H. Liu、Roland Bonneau、Matthew S. Platz

  DOI：10.1021/ja00199a076

  日期：1989.8