| 178114-70-0

• CAS: 178114-70-0
• 化学式: C₃₇H₃₁ClOP₂Pd
• 分子量: 695.473
• InChiKey: VXGMJNCZVNMFPX-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  乙腈 、 、 silver tetrafluoroborate 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Copolymerization of ethylene and carbon monoxide by phosphinite-modified palladium catalysts

  摘要：

  Novel palladium complexes with bidentate phosphinite and mixed phosphine-phosphinite ligands of the general formula [((PP)-P-Lambda)Pd(Me)Cl] were prepared. After halide abstraction, these complexes are highly active catalysts for the copolymerization of ethylene and CO, yielding high molecular weight polyketones with activities of up to 30000 mol per mol Pd. The preference of cis- or cans-coordination, depending on the chelate ring size, was investigated. In complexes with up to 11-membered chelates, a cis-fixation of the ligands is observed, whereas bigger chelates afforded catalytically inactive trans-complexes.

  DOI：

  10.1016/0022-328x(95)06046-y
• 作为产物：
  描述：

  chloromethyl(1,5-cyclooctadiene)palladium(II) 、 以 苯 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Copolymerization of ethylene and carbon monoxide by phosphinite-modified palladium catalysts

  摘要：

  Novel palladium complexes with bidentate phosphinite and mixed phosphine-phosphinite ligands of the general formula [((PP)-P-Lambda)Pd(Me)Cl] were prepared. After halide abstraction, these complexes are highly active catalysts for the copolymerization of ethylene and CO, yielding high molecular weight polyketones with activities of up to 30000 mol per mol Pd. The preference of cis- or cans-coordination, depending on the chelate ring size, was investigated. In complexes with up to 11-membered chelates, a cis-fixation of the ligands is observed, whereas bigger chelates afforded catalytically inactive trans-complexes.

  DOI：

  10.1016/0022-328x(95)06046-y