(η5-C5H5)(CO)2MnC(P(C6H5)2CH3)C2(C6H5)2 | 1338096-35-7

• 英文名称: (η5-C5H5)(CO)2MnC(P(C6H5)2CH3)C2(C6H5)2
• CAS: 1338096-35-7
• 化学式: C₃₅H₂₈MnO₂P
• 分子量: 566.518
• InChiKey: JOUJXVHWRUTCJL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  四氟硼酸-二乙醚络合物 、 (η5-C5H5)(CO)2MnC(P(C6H5)2CH3)C2(C6H5)2 以 二氯甲烷 为溶剂， 以74%的产率得到(η5-C5H5)(CO)2MnCH(P(C6H5)2CH3)C2(C6H5)2(BF4)
  参考文献：
  名称：

  Protonation of manganese phosphonioallenyl complexes

  摘要：

  The addition of phosphines to the manganese allenylidene complexes Cp(CO)(2)Mn=C=C=C(Ph)R (R-H, Ph) proceeds selectively at the C-alpha atom to result in the alpha-phosphonioallenyl complexes Cp(CO)(2)Mn -C((PR31)-P-broken vertical bar)=C=C(Ph) R. The protonation of the latter affords the eta(2)-(1,2)- phosphonioallenes Cp(CO)(2)Mn{eta(2)-(1,2)- HC((+PR31))]=C=C(Ph)R}, rather than the phosphoniovinylcarbenes Cp(CO)(2)Mn= C((+PR31))-HC=C(Ph)R. All complexes obtained are stereochemically rigid and do not isomerize into the eta(2)-(2,3)-phosphonioallene isomers. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.07.034
• 作为产物：
  描述：

  Ph2-allylidene cymantrene 、 二苯基甲氧基膦 以 正己烷 为溶剂， 以79%的产率得到(η5-C5H5)(CO)2MnC(P(C6H5)2CH3)C2(C6H5)2
  参考文献：
  名称：

  Protonation of manganese phosphonioallenyl complexes

  摘要：

  The addition of phosphines to the manganese allenylidene complexes Cp(CO)(2)Mn=C=C=C(Ph)R (R-H, Ph) proceeds selectively at the C-alpha atom to result in the alpha-phosphonioallenyl complexes Cp(CO)(2)Mn -C((PR31)-P-broken vertical bar)=C=C(Ph) R. The protonation of the latter affords the eta(2)-(1,2)- phosphonioallenes Cp(CO)(2)Mn{eta(2)-(1,2)- HC((+PR31))]=C=C(Ph)R}, rather than the phosphoniovinylcarbenes Cp(CO)(2)Mn= C((+PR31))-HC=C(Ph)R. All complexes obtained are stereochemically rigid and do not isomerize into the eta(2)-(2,3)-phosphonioallene isomers. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.07.034