Synthesis and characterisation of [Ru<sub>3</sub>(CO)<sub>9</sub>(µ<sub>3</sub>-η<sup>2</sup>:η<sup>2</sup>:η<sup>2</sup>-C<sub>6</sub>H<sub>6</sub>)]
作者:Brian F. J. Johnson、Jack Lewis、Marcia Martinelli、Anthony H. Wright、Dario Braga、Fabrizia Grepioni
DOI:10.1039/c39900000364
日期:——
The cluster benzene complex [Ru3(CO)9(µ3-η2:η2:η2-C6H6)] which contains a benzene ligand in a face-capping co-ordination mode has been prepared, and its molecular structure investigated by a single crystal X-ray analysis which provides unambiguous evidence for CâC length alternation.
我们制备了簇状苯配合物[Ru3(CO)9(µ3-δ-2:δ-2:δ-2-C6H6)],该配合物含有面帽配位模式的苯配体,并通过单晶 X 射线分析研究了其分子结构,该分析提供了 CâC 长度交替的明确证据。