[Ru(4-t-butyl-2,6-di(8'-hydroxy-quinolin-2'-yl)pyridine)(4-picoline)2](PF6) | 1338559-34-4

• 英文名称: [Ru(4-t-butyl-2,6-di(8'-hydroxy-quinolin-2'-yl)pyridine)(4-picoline)2](PF6)
• CAS: 1338559-34-4
• 化学式: C₃₉H₃₅N₅O₂Ru*F₆P
• 分子量: 851.773
• InChiKey: ICBSAVVAFHPRFD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ru(4-t-butyl-2,6-di(8'-hydroxy-quinolin-2'-yl)pyridine)(4-picoline)2](PF6) 在 ascorbic acid 作用下， 以 氘代甲醇 为溶剂， 生成 [Ru(4-t-butyl-2,6-di(8'-hydroxy-quinolin-2'-yl)pyridine)(4-picoline)2]
  参考文献：
  名称：

  Polydentate Analogues of 8-Hydroxyquinoline and Their Complexes with Ruthenium

  摘要：

  Selective reduction of 2-nitro-3-methoxybenzaldehyde provides 2-amino-3-methoxybenzaldehyde that undergoes the Friedlander condensation with a variety of acetyl-substituted derivatives of pyridine and 1,10-phenanthroline. After cleavage of the methyl ether, the resulting polydentate analogues of 8-hydroxyquinoline are excellent ligands for ruthenium. The resulting oxidation state of the metal center depends on the anionic character of the ligands. The presence of two electron donating anionic ligands results in a Ru(III) complex as evidenced by paramagnetic NMR behavior. The electronic absorption and redox properties of the complexes were measured and found to be consistent with the anionic character of the 8-HQ moieties. A planar pentadentate ligand provides two Ru-O and two Ru-N bonds in the equatorial plane. An X-ray structure shows that the central pyridine of the ligand is oriented toward the metal but held at a distance of 2.44 angstrom.

  DOI：

  10.1021/ic201524j
• 作为产物：
  描述：

  4-甲基吡啶 、 ammonium hexafluorophosphate 、 dichlorotetrakis(dimethylsulfoxide)ruthenium(II) 、 4-t-butyl-2,6-di(8'-hydroxy-quinolin-2'-yl)pyridine 在 NaOH 、 triethylamine 、 LiCl 作用下， 以 乙醇 为溶剂， 以29%的产率得到[Ru(4-t-butyl-2,6-di(8'-hydroxy-quinolin-2'-yl)pyridine)(4-picoline)2](PF6)
  参考文献：
  名称：

  Polydentate Analogues of 8-Hydroxyquinoline and Their Complexes with Ruthenium

  摘要：

  Selective reduction of 2-nitro-3-methoxybenzaldehyde provides 2-amino-3-methoxybenzaldehyde that undergoes the Friedlander condensation with a variety of acetyl-substituted derivatives of pyridine and 1,10-phenanthroline. After cleavage of the methyl ether, the resulting polydentate analogues of 8-hydroxyquinoline are excellent ligands for ruthenium. The resulting oxidation state of the metal center depends on the anionic character of the ligands. The presence of two electron donating anionic ligands results in a Ru(III) complex as evidenced by paramagnetic NMR behavior. The electronic absorption and redox properties of the complexes were measured and found to be consistent with the anionic character of the 8-HQ moieties. A planar pentadentate ligand provides two Ru-O and two Ru-N bonds in the equatorial plane. An X-ray structure shows that the central pyridine of the ligand is oriented toward the metal but held at a distance of 2.44 angstrom.

  DOI：

  10.1021/ic201524j