Pd(η(5)-C5H5)Fe(η(5)-C5H3CH=N(C6H3-2-Me)-4-(C6H3-2'-Me)-N=CH(η(5)-C5H4)Fe(η(5)-C5H5))(PPh3) | 186822-76-4

• 英文名称: Pd(η(5)-C5H5)Fe(η(5)-C5H3CH=N(C6H3-2-Me)-4-(C6H3-2'-Me)-N=CH(η(5)-C5H4)Fe(η(5)-C5H5))(PPh3)
• CAS: 186822-76-4
• 化学式: C₅₄H₄₆ClFe₂N₂PPd
• 分子量: 1007.51
• InChiKey: UIWBDMCJHUBXHP-CDWLHPPHSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Pd(η(5)-C5H5)Fe(η(5)-C5H3CH=NC6H3-2-Me)-4-(C6H3-2'-Me)-N=CH(η(5)-C5H4)Fe(η(5)-C5H5)(μ-Cl)]2 、 三苯基膦 以 苯 为溶剂， 以68%的产率得到Pd(η(5)-C5H5)Fe(η(5)-C5H3CH=N(C6H3-2-Me)-4-(C6H3-2'-Me)-N=CH(η(5)-C5H4)Fe(η(5)-C5H5))(PPh3)
  参考文献：
  名称：

  Mono- and bis(cyclopalladation) of bis(ferrocenylimine)[(η5-C5H5)Fe(η5-C5H4)CHN (C6H3-2-CH3)−]2

  摘要：

  The reaction of the novel bis(ferrocenylimine) [(eta(5)-C5H5)Fe{(eta(5)-C5H4)-CH=N-(C6H3-2-CH3)-}](2) (1) with Na-2[PdCl4] and NaCH3COO . 3H(2)O in methanol in a 1:2:2 or a 1:1:1 molar ratio produces the polynuclear di-mu-chloro-bridged cyclopalladated compounds [Pd-2(eta(5)-C5H5)Fe[(eta(5)-C5H3)-CH=N-(C6H3-2-CH3)-]}(2)(mu-Cl)(2)](2) (2a) or [Pd{(eta(5)-C5H5)Fe[(eta(5)-C5H3)-CH=N-C6H3- 2-(CH3)-4-{(C6H3-2'-CH3)-N=CH-(eta(5)-C5H4)}]Fe(eta(5)-C5H5)}(mu-Cl)](2) (2b) respectively, which arise from the activation of two (for 2a) or one (for 2b) sigma(C-sp2,C-ferrocene-H) bonds. Addition of triphenylphosphine to benzene suspensions of compounds 2 produces the cleavage of the 'Pd(mu-Cl)(2)Pd' units and the formation of [Pd-2{eta(5)-C5H5)Fe[(eta(5)-C5H3)-CH=N-(C6H3-2-CH3)-]}Cl-2(2)(PPh(3))(2)] (3a), or [Pd{(eta(5)-C5H5)Fe[(eta(5)-C5H3)-CH=N-C6H3-2-(CH3)-4-{C6H3-(2'-CH3)-N=CH-(eta(5)-C5H4)}]Fe(eta(5)-C5H5)}Cl(PPh(3))] (3b) Proton and P-31 NMR studies on compounds 3 confirm the existence of two (in 3a) or one (in 3b) five-membered palladocycles fused with the ferrocenyl units, and a trans arrangement of the PPh(3) ligand and the imine nitrogen. Electrochemical studies of these compounds are also reported.

  DOI：

  10.1016/s0022-328x(96)06404-2