hydrated thallium(1+) | 61003-61-0

• 英文名称: hydrated thallium(1+)
• 英文别名: Thallium(1+);hydrate
• CAS: 61003-61-0
• 化学式: (x)H₂O*Tl
• 分子量: 222.399
• InChiKey: QGYXCSSUHCHXHB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.21
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  水 、 thallium(III) nitrate 在 humic acid 作用下， 反应 72.0h， 生成 hydrated thallium(1+)
  参考文献：
  名称：

  An Experimental Study of Stabilization of Trivalent Thallium by Natural Organic Matter

  摘要：

  Stabilization of dissolved trivalent thallium, Tl(III), in water by complexation with humic acid and its analogue (poly(acrylic acid), PAA) was studied. Chromatographic analysis showed that Tl(III) was stabilized by the complexation, which allowed us to estimate the stability constant of Tl(III)–humate complex. Cyclic voltammograms of Tl showed that the redox potential of Tl(III)/Tl(I) redox couple in the presence of PAA was lower than that without PAA. These results suggest that Tl(III) can be present in natural water by the stabilization of Tl(III) rather than Tl(I) due to the formation of humate complex.

  DOI：

  10.1246/cl.150551