(η5-cyclopentadienyl)cobalt(III)(cyanide)2(triphenylphosphine) | 38531-03-2

• 英文名称: (η5-cyclopentadienyl)cobalt(III)(cyanide)2(triphenylphosphine)
• 英文别名: CpCo(CN)2(PPh3)
• CAS: 38531-03-2
• 化学式: C₂₅H₂₀CoN₂P
• 分子量: 438.414
• InChiKey: FICXNPMTBDAELS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  三氯化铝 、 (η5-cyclopentadienyl)cobalt(III)(cyanide)2(triphenylphosphine) 以 乙腈 为溶剂， 生成 [CpCo(PPh3)(μ-CN)2CoCl2]2
  参考文献：
  名称：

  Mixed metal cyanide complexes derived from the CpCo(CN)3− anion

  摘要：

  Reaction of the salt KCpCo(CN)(3) (1) with zinc iodide leads to the formation of a highly insoluble Co(III)/Zn(II) polymeric chain. However, pyridine was found to disrupt the aggregate that is formed to yield a crystalline trimetallic complex consisting of two CpCo(CN)(3) anions bridging a Zn(py)(4) dication through the cyanide ligands, [CpCo(CN)(2)(mu-CN)](2)Zn(py)(4) (2). Along these same lines, reaction of CpCo(CN)(2)PPh3 (3) with AlCl3 or CoCl2 leads to the formation of a highly crystalline Co(II)/Co(III) diamond. [CpCo(PPh3)(mu-CN)(2)CoCl2](2) (4). Molecular Structures of 1, 2, 3 and 4 were determined by single-crystal X-ray crystallography. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.11.016
• 作为产物：
  描述：

  (η5-cyclopentadienyl)cobalt(cyanide)(triphenylphosphine)*BF3 在 methanol 作用下， 生成 (η5-cyclopentadienyl)cobalt(III)(cyanide)2(triphenylphosphine)
  参考文献：
  名称：

  Carter, Stephen J.; Stuhl, Louis S., Organometallics, 1988, vol. 7, # 9, p. 1909 - 1918

  摘要：

  DOI：

文献信息

• Paramagnetic organometallic complexes. Synthesis of 17-electron cyclopentadienylcobalt complexes
  作者：Ronald J. McKinney

  DOI：10.1021/ic00135a065

  日期：1982.5