η3-Ligation of tetrathiamacrocycles to Mo and W: Structures of [WI(CO)3{η3-(Me8[16]aneS4)}]-[WI3(CO)4] and [WI(CO)2{η4-(Me8[16]aneS4)}][WI3(CO)4] (Me8[16]aneS4 = 3,3,7,7,11,11,15,15-octamethyl-1,5,9,13-tetrathiacyclohexadecane)
作者:Paul K. Baker、Marcus C. Durrant、Beatrix Goerdt、Sharman D. Harris、David L. Hughes、Raymond L. Richards
DOI:10.1016/0022-328x(94)80093-6
日期:1994.4
Reaction of [WI2(CO)3(MeCN)2] with Me8[16]aneS4 gives [WI(CO)3eta3-(Me8[16]aneS4)}[WI3(CO)4] and [WI(CO)2eta4-(Me8[16]aneS4)}][WI3(CO)4], whose crystal structures have been determined; [Mo(CO)3(MeCN)3] reacts with [16]aneS4 to give [Mo(CO)3eta3-([16]aneS4)}].