| 1003892-42-9

• CAS: 1003892-42-9
• 化学式: C₃₀H₃₀BCl₂N₃Pt
• 分子量: 709.385
• InChiKey: KOKGYIICJBUBEL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 (6-Pyrrolo[2,3-b]pyridin-1-ylpyridin-3-yl)-bis(2,4,6-trimethylphenyl)borane 生成
  参考文献：
  名称：

  Ambient-Temperature Metal-to-Ligand Charge-Transfer Phosphorescence Facilitated by Triarylboron:  Bnpa and Its Metal Complexes

  摘要：

  A Cu(I) complex, 1, and a Pt(II) complex, 2a, of a triarylboron ligand, Bnpa, with bright ambient-temperature phosphorescence have been obtained. The phosphorescence of these complexes is highly sensitive toward molecular oxygen and has a distinct response to fluoride ions. For 1, the fluoride ion causes phosphorescent quenching and Bnpa dissociation, and for 2a, it switches phosphorescent color from yellow to green. The Cu(I) complex has an exceptionally high emission quantum yield (0.88) in the solid state.

  DOI：

  10.1021/ic7021215