| 310871-61-5

• CAS: 310871-61-5
• 化学式: C₂₃H₂₆N₃PPd*Cl₄Zn
• 分子量: 689.075
• InChiKey: FZRUDAXLDNMBRN-FAJPTTPKSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 以 乙腈 为溶剂， 以94%的产率得到
  参考文献：
  名称：

  A palladium(II) complex of a new iminophosphine ligand derived from diethylenetriamine and 2-(diphenylphosphino)benzaldehyde

  摘要：

  The mononuclear complexes [Pd(oPdien)]X-2 {oPdien = N-(2-diphenylphosphinobenzylidene)diethylenetriamine: (4a) X-2 = [ZnCl4](2-); (4b) X = [PF6](-); (4c) X = Cl-} are described. Complex 4a formed in high yield when [Pd(oPCHO)(2)Cl-2][oPCHO = 2-(diphenylphosphino)benzaldehyde] (1) and [Zn(dien)Cl-2] (2) were reacted together in an unsuccessful attempt to template formation of a bimetallic iminophosphine-bridged complex. The X-ray crystal structure of 4b has been determined. The ligand oPdien is the first iminophosphine derived from dien and has been isolated and used to prepare 4c. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00181-x
• 作为产物：
  描述：

  trans-[PdCl2(o-diphenylphosphinobenzaldehyde)2] 、 {Zn(II)(diethylenetriamine)Cl}Cl 以 乙醇 为溶剂， 以81%的产率得到
  参考文献：
  名称：

  A palladium(II) complex of a new iminophosphine ligand derived from diethylenetriamine and 2-(diphenylphosphino)benzaldehyde

  摘要：

  The mononuclear complexes [Pd(oPdien)]X-2 {oPdien = N-(2-diphenylphosphinobenzylidene)diethylenetriamine: (4a) X-2 = [ZnCl4](2-); (4b) X = [PF6](-); (4c) X = Cl-} are described. Complex 4a formed in high yield when [Pd(oPCHO)(2)Cl-2][oPCHO = 2-(diphenylphosphino)benzaldehyde] (1) and [Zn(dien)Cl-2] (2) were reacted together in an unsuccessful attempt to template formation of a bimetallic iminophosphine-bridged complex. The X-ray crystal structure of 4b has been determined. The ligand oPdien is the first iminophosphine derived from dien and has been isolated and used to prepare 4c. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00181-x