| 160860-39-9

• CAS: 160860-39-9
• 化学式: C₂₀H₅₄ClN₃Si₅Zr
• 分子量: 603.773
• InChiKey: AUDCROVNOORKGA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 bis(trimethylsilyl)methyllithium 以 乙醚 为溶剂， 以55%的产率得到
  参考文献：
  名称：

  Zirconium complexes incorporating the new tridentate diamide ligand [(Me₃Si)N{CH₂CH₂N(SiMe₃)}₂]^2–(L); the crystal structures of [Zr(BH₄)₂L] and [ZrCl{CH(SiMe₃)₂}L]

  摘要：

  The lithium complex of the sterically demanding, polyfunctional amide ligand [(Me3Si)N-{CH2CH2N(SiMe3)}2]2-, Li2L reached with [ZrCl4(thf)2] (thf = tetrahydrofuran) to form dimeric [(ZrCl2L)2] 2, in which the ligand is facially co-ordinated in a tridentate manner. Treatment of 2 with LiBH4 or Li[CH(SiMe3)2] generated [Zr(H3BH)L] 3 and [ZrCl{CH(SiMe3)2}L] 4, respectively. Variable-temperature NMR studies on 4 give evidence for restricted rotation of both the alkyl and amino SiMe3 groups. The crystal structures of 3 and 4 have been determined.

  DOI：

  10.1039/dt9950000025