diferrocenyl(trityloxy)cyclopropenylium tetrafluoroborate | 862772-15-4

• 英文名称: diferrocenyl(trityloxy)cyclopropenylium tetrafluoroborate
• CAS: 862772-15-4
• 化学式: BF₄*C₄₂H₃₃Fe₂O
• 分子量: 752.222
• InChiKey: XOHOGSNJSAFTAS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  哌啶 、 diferrocenyl(trityloxy)cyclopropenylium tetrafluoroborate 以 二氯甲烷 为溶剂， 生成 diferrocenyl(piperidino)cyclopropenylium tetrafluoroborate
  参考文献：
  名称：

  Diferrocenylcyclopropenyl cations. Synthesis, structures, and some chemical properties

  摘要：

  Synthesis of diferrocenyleyclopropenyl tetrafluoroborates with hetero-substituents in the three-membered ring, viz., ethoxy, trityloxy, ferrocenyl(phenyl)methoxy, N,N-diethylamino, piperidino, and morpholino, is described. The spatial structure of diferrocenyl(morpholino)cyclopropenyl tetralluoroborate was established based on the data from X-ray diffraction analysis. Under the action of potassium tert-butoxide, all the diferrocenylcyclopropenyl tetrafluoroborates undergo three-membered ring-opening with formation of the corresponding 2,3-diferrocenylacrylic acid derivatives. A mechanism of the ring-opening is suggested. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.04.014
• 作为产物：
  描述：

  2,3-diferrocenylcyclopropenone 、 trityl tetrafluoroborate 以 二氯甲烷 为溶剂， 以85%的产率得到diferrocenyl(trityloxy)cyclopropenylium tetrafluoroborate
  参考文献：
  名称：

  Diferrocenylcyclopropenyl cations. Synthesis, structures, and some chemical properties

  摘要：

  Synthesis of diferrocenyleyclopropenyl tetrafluoroborates with hetero-substituents in the three-membered ring, viz., ethoxy, trityloxy, ferrocenyl(phenyl)methoxy, N,N-diethylamino, piperidino, and morpholino, is described. The spatial structure of diferrocenyl(morpholino)cyclopropenyl tetralluoroborate was established based on the data from X-ray diffraction analysis. Under the action of potassium tert-butoxide, all the diferrocenylcyclopropenyl tetrafluoroborates undergo three-membered ring-opening with formation of the corresponding 2,3-diferrocenylacrylic acid derivatives. A mechanism of the ring-opening is suggested. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.04.014