[Ag(bis(4-pyridyl)amine)]PF6*MeCN | 911639-44-6

• 英文名称: [Ag(bis(4-pyridyl)amine)]PF6*MeCN
• CAS: 911639-44-6
• 化学式: Ag*C₂H₃N*C₁₀H₉N₃*F₆P
• 分子量: 465.086
• InChiKey: QOYDHGQHGOAWHA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4,4,-二吡啶胺 、 六氟磷酸银 、 乙腈 以 水 、 异丙醇 、 乙腈 为溶剂， 生成 [Ag(bis(4-pyridyl)amine)]PF6*MeCN
  参考文献：
  名称：

  Helices versus Zigzag Chains:  One-Dimensional Coordination Polymers of Ag^I and Bis(4-pyridyl)amine

  摘要：

  Five one-dimensional coordination polymers were prepared by the reaction of a bent bridging ligand, bis(4-pyridyl)-amine (bpa), with an extensive series of AgX salts (X = CF3SO3, PF6, ClO4, NO3). The 1D polymer networks formed with AgCF3SO3 (1), AgPF6 (2 center dot MeCN), and AgClO4 (3 center dot 2MeCN) all incorporated MeCN and were found to adopt a zigzag arrangement. The networks formed with AgClO4 (4) and AgNO3 (5) did not contain any solvent and adopted a single-stranded helical arrangement. Two-dimensional H-bonding networks were formed for 1 and 3, 2MeCN, with network topologies 4.8(2) and (4, 4), respectively, whereas three-dimensional H-bonded networks of helices were formed for 4, showing an (8, 3)-a network topology, and 5, showing the topology of the R-polonium net. The three-dimensional networks both exhibited 4-fold interpenetration. The NO3- anion in 5 appeared to be acting as a template for the 3D structure.

  DOI：

  10.1021/ic060487y