TiCl4(ammonia) | 166820-89-9

• 英文名称: TiCl4(ammonia)
• CAS: 166820-89-9
• 化学式: Cl₄H₃NTi
• 分子量: 206.723
• InChiKey: ZHTOIEDMLUUKDZ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  2.92
• 重原子数：
  6.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  35.0
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  氨 、 四氯化钛 以 gaseous matrix 为溶剂， 生成 Azane;titanium(4+);tetrachloride 、 TiCl4(ammonia)
  参考文献：
  名称：

  Infrared Spectroscopic Study of the Cryogenic Thin Film and Matrix-Isolated Complexes of TiCl4 with NH3 and (CH3)3N

  摘要：

  The matrix isolation technique and infrared spectroscopy have been used to isolate and characterize for the first time the 1:1 complex of TiCl4 with NH3. Intense spectral features at 440 and 457 cm(-1) were assigned to the Ti-CI antisymmetric stretching modes in this complex; the NH3 symmetric deformation was observed above 1200 cm(-1), shifted over 200 cm(-1) from the parent band position. The spectra suggest a trigonal bipyramidal arrangement about the central titanium with the NH3 ligand in an axial position. A similar set of product bands was observed for the 1:1 complex of TiCl4 with (CH3)(3)N, a species which had been observed previously but not fully characterized. Cryogenic thin film experiments with subsequent warming led to the formation of the 1:1 complex and further reaction products, including the 1:2 complex and two or more amido and/or imido complexes.

  DOI：

  10.1021/ic00121a016

文献信息

• Reaction Process of Titanium Tetrachloride with Ammonia in the Vapor Phase and Properties of the Titanium Nitride Formed
  作者：Yuzo Saeki、Ryoko Matsuzaki、Akimasa Yajima、Masayo Akiyama

  DOI：10.1246/bcsj.55.3193

  日期：1982.10

  On donne les produits de reaction obtenus aux diverses temperatures. Mecanisme: il y a d'abord formation de ZrCl 4 •2NH 3 , puis ZrClN. Au-dessus de 1000°C, ZrN x est forme

  Donne les produits de reaction obtenus aux 不同温度。机制：il ya d'abord 地层 de ZrCl 4 •2NH 3 ，puis ZrClN。Au-dessus de 1000°C, ZrN x est forme
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ti: MVol., 5.4, page 271 - 285
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• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ti: MVol., 5.21, page 405 - 411
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• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ti: MVol., 5.6.4, page 312 - 317
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• Staehler, A., Chemische Berichte, 1905, vol. 38, p. 2629
  作者：Staehler, A.

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  日期：——