| 339189-44-5

• CAS: 339189-44-5
• 化学式: C₉₀H₅₈Cu₂O₁₂
• 分子量: 1458.54
• InChiKey: MBVJCALVZSUURY-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-萘酚 、 双氧水 、 cis-bis(glycinato)copper(II) monohydrate 以 水 、 乙腈 为溶剂， 生成 、
  参考文献：
  名称：

  Oxidative oligomerisation of 2-naphthol by cis-bis(glycinato)copper(II)

  摘要：

  The reaction of 2-naphthol with tert-butylhydroperoxide by cis-bis(glycinato)copper(II) oligomerises 2-naphthol. One of the isolated tetramer A contains a tert-butyloxy group. Similar reaction of 2-naphthol with hydrogen peroxide in the presence of cis-bis(glycinato) copper(II) oligomerises 2-naphthol gives tetramer through hydroxylative oligomerisation. The oligomers are bound to ore-bridged copper cores to give B and C. These oligomers exhibit thermal sensing property. The oligomer (B) converts benzamide to benzoic acid, as well as catalyses oxidation of aromatic aldehydes such as benzaldehyde to corresponding acids. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(00)00434-9