| 353496-95-4

• CAS: 353496-95-4
• 化学式: BF₄*C₃₀H₃₈N₃OPRe
• 分子量: 760.637
• InChiKey: OLTQDSFHSKNFHQ-UHFFFAOYSA-O

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (η5-C5H5)(Me)(NO)(PPh3)rhenium(II) 、 N,N-二乙基乙二胺 、 trityl tetrafluoroborate 以 二氯甲烷 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  A New Family of Chiral Chelating Diamines with Transition-Metal Stereocenters:  Synthesis, Structure, and Reactivity of the Enantiomerically Pure Dirhenium-Substituted 1,2-Diamine (η⁵-C₅H₅)Re(NO)- (PPh₃)(CH₂N(CH₃)CH₂CH₂(H₃C)NCH₂)(Ph₃P)(ON)Re(η⁵-C₅H₅)

  摘要：

  Reaction of enantiopure (S)-(eta (5)-C5H5)Re(NO)(PPh3)(CH3) ((S)-1) with Ph3C(+)BF(4)(-)(1 equiv) and then the N,N ' -dimethyl 1,2-diamine HN(CH3)CH2CH2(H3C)NH (0.5 equiv) gives the diammonium salt (SReSRe)-[(eta (5)-C5H5)Re(NO)(PPh3)(CH2NH(CH3)CH2CH2(H3C)HNCH2)(Ph3P)(ON)Re(eta (5)-C5H5)](2+)(BF4- (94%) as a mixture of Re/N configurational diastereomers. Reaction with t-BuOK yields the title compound (SReSRe)-4 (66%) as an air-stable orange powder. Reaction with (PhCN)(2)PdCl2 gives a single diastereomer of a chelate complex, (SReRNRNSRe)-[(eta (5)-C5H5)Re(NO)(PPh3)-(CH2N(CH3)CH2CH2(H3C)NCH2)(Ph3P)(ON)Re(eta (5)-C5H5)]PdCl2 (80%), the configuration and approximate Ca symmetry of which has been established crystallographically. Racemic 1, Ph3C+BF4- (1 equiv), and the N,N ' -dimethyl 1,2-diamine HN(CH2CH3)CH2CH2(H3CCH2)NH (1 equiv) give [(eta (5)-C5H5)Re(NO)(PPh3)(CH2NH(CH2CH3)CH2CH2NH(CH2CH3))]+BF4-, and the crystal structure of the SReSN,RReRN diastereomer is determined. The ReCH2N conformations of the preceding compounds, and their influence upon the diastereoselectivities, are analyzed in detail.

  DOI：

  10.1021/om010153a