chloro[[1-methyl-1-(6-methyl-2-pyridyl)ethoxy]diphenylphosphine-κ2N,P]methylpalladium(II) | 912552-73-9

• 英文名称: chloro[[1-methyl-1-(6-methyl-2-pyridyl)ethoxy]diphenylphosphine-κ2N,P]methylpalladium(II)
• CAS: 912552-73-9
• 化学式: C₂₂H₂₅ClNOPPd
• 分子量: 492.293
• InChiKey: NQIALVKYNVNQAF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  chloromethyl(1,5-cyclooctadiene)palladium(II) 、 2-ethyl-6-methyl-[1'-methyl-1'-oxy(diphenylphosphino)]pyridine 以 二氯甲烷 为溶剂， 生成 chloro[[1-methyl-1-(6-methyl-2-pyridyl)ethoxy]diphenylphosphine-κ2N,P]methylpalladium(II)
  参考文献：
  名称：

  New palladium complexes with phosphino- and phosphinitopyridine ligands

  摘要：

  Three new palladium complexes containing a difunctional P, N-chelate, namely tris(chloro{[1-methyl-1-(6-methyl-2-pyridyl) ethoxy] diphenylphospine-kappa(2) N, P} methylpalladium( II) chloroform solvate, 3[Pd(CH3) Cl(C21H22NOP)] center dot CHCl3, (III), dichloro[2-(2,6-dimethylphenyl)-6-(diphenylphosphinomethyl) pyridine-kappa(2) N, P] palladium(II), [PdCl2(C26H24NP)], (IV), and chloro[2-(2,6-dimethylphenyl)-6-(diphenylphosphinomethyl) pyridine- kappa(2) N, P] methylpalladium(II), [Pd(CH3) Cl( C26H24NP)], ( V), are reported. Geometric data and the conformations of the ligands around the metal centers, as well as slight distortions of the Pd coordination environments from idealized square-planar geometry, are discussed and compared with the situations in related compounds. Non-conventional hydrogen-bond interactions (C - H center dot center dot center dot Cl) have been found in all three complexes. Compound ( III) is the first six-membered chloro - methyl - phosphinite P, N-type Pd-II complex to be structurally characterized.

  DOI：

  10.1107/s0108270106001296