[Pd(η3-C4H7)(C6H5CN)2][ClO4] | 303197-67-3

• 英文名称: [Pd(η3-C4H7)(C6H5CN)2][ClO4]
• CAS: 303197-67-3
• 化学式: C₁₈H₁₇N₂Pd*ClO₄
• 分子量: 467.217
• InChiKey: UPWVDDDFPWMVGH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (bis(diphenylphosphino)ethane)(1,2-ethanedithiolato)platinum(II) 、 [Pd(η3-C4H7)(C6H5CN)2][ClO4] 以 甲醇 为溶剂， 以45%的产率得到[(1,2-bis(diphenylphosphino)ethane)Pt(μ-SCH2CH2S)2Pd(η3-C4H7)][ClO4]
  参考文献：
  名称：

  Synthesis and characterization of heterodinuclear thiolate complexes containing the Pd(η3-allyl)+ moiety. Crystal structure of [(dppe)Pd(μ-SC6H4Me-p)2Pd(η3-C3H5)][ClO4]

  摘要：

  Hetero dinuclear complexes of the types [(dppe)M(mu-SR)(2)Pd(eta(3)-allyl)][ClO4] (M = Pd or Pt) and [(dppe)Pt(mu-SC2H4S)Pd(eta(3)-allyl)][ClO4] [dppe = 1,2-bis(diphenylphosphino)ethane; allyl = C3H5 or C4H7] have been obtained by reaction of the corresponding cis-dithiolato complexes, [M(SR)(2) (dppe)] or [Pt(SC2H4S)(dppe)]. and [Pd(eta(3)-allyl)(PhCN)(2)][ClO4]. The identity of these complexes has been established by NMR (H-1 and P-31) spectroscopy. The crystal structure of [(dppe)Pd(mu-SC6H4Me-p)(2)Pd(eta(3)-C3H5)][ClO4] has been determined by single-crystal X-ray methods. The p-tolyl groups on the sulfur atoms adopt a syn conformation with respect to the central Pd-S-2-Pd core. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00440-x