trans-[PtCl(NH3)(HN=C(NH2)Ph)2]Cl | 852926-45-5

• 英文名称: trans-[PtCl(NH3)(HN=C(NH2)Ph)2]Cl
• CAS: 852926-45-5
• 化学式: C₁₄H₁₉ClN₅Pt*Cl
• 分子量: 523.324
• InChiKey: VRZGEJHMZHRTGT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氨 、 trans-bis(benzonitrile)dichloroplatinum(II) 以 二氯甲烷 为溶剂， 以82.8%的产率得到trans-[PtCl(NH3)(HN=C(NH2)Ph)2]Cl
  参考文献：
  名称：

  Synthesis and characterisation of the amidine complexes trans-[PtCl(NH3){HNC(NH2)R}2]Cl (R=Me, Ph, CH2Ph) derived from addition of NH3 to the coordinated nitriles in trans-[PtCl2(NCR)2]

  摘要：

  The di-nitrile complexes trans-[PtCl2(N CR)(2)] (R = Me, Ph, CH2Ph) react with an excess of gaseous NH3 in CH2Cl2 at -10 degrees C to form, in high yield, the corresponding di-amidine complexes trans-[PtCl(NH3){HN=C(NH2)R}(2)]Cl in which also one chlorine ligand has been displaced by NH3. The H-1 NMR spectra in DMSO showed the formation of different species which were characterized through NOESY, TOCSY and H-1/C-13 heteronuclear correlations as trans-[Pt(NH3){HN=C(NH2)R}(2)(DMSO)]Cl-2 and trans-[PtCl{HN=C(NH2)R}(2)(DMSO)]Cl. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.01.005