{(η6-p-MeC6H4CHMe2)RuCl2(2-mercapto-2-thiazoline)} * CH2Cl2 | 149830-82-0

• 英文名称: {(η6-p-MeC6H4CHMe2)RuCl2(2-mercapto-2-thiazoline)} * CH2Cl2
• CAS: 149830-82-0
• 化学式: CH₂Cl₂*C₁₃H₁₉Cl₂NRuS₂
• 分子量: 510.341
• InChiKey: XJKCPSFSOUVJJX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-巯基噻唑啉 、 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 在 CH₂Cl₂ 作用下， 以 甲醇 为溶剂， 以96%的产率得到{(η6-p-MeC6H4CHMe2)RuCl2(2-mercapto-2-thiazoline)} * CH2Cl2
  参考文献：
  名称：

  Di- and trinuclear (η6-arene)ruthenium(II) complexes containing bridging heterocyclic thioamides

  摘要：

  Reaction of [(eta6-p-MeC6H4CHMe2)2RuCl2]2 With the heterocyclic thioamides (L), 2-mercapto-1-methylimidazole (mmimH) or 4,5-diphenyl-2-mercaptoimidazole (dpmimH2) in a 1:1 ratio in the presence of base leads to the formation of the dinuclear complexes [eta6-p-MeC6H4CHMe2)2Ru2(mu-L)(mu-Cl)Cl]CI (3 and 4). The [dpmimH]-ligand in 4 adopts a mu2-(1kappa1S; 2kappa2N,S) bridging mode, as is also observed for one of the [mtz]- ligands (mtzH=2-mercapto-2-thiazoline) in [(eta6-C6H6)2RU2(mu-mtz)2Cl]Cl (2). In contrast, the second bridging [mtz]- ligand in 2 exhibits the mu2-N,S coordination mode. The pentadentate [dpmimH-1]3- ligand bridges three ruthenium atoms in the trinuclear complex [(eta6-p-MeC6H4CHMe2)3Ru3(mu3-dpmimH-1)(mu-Cl)Cl2] (6), two of which via the mu2-(1kappa1S; 2kappa2N,S) coordination mode displayed by 4. A cyclometallation leads to the coordination of the third ruthenium atom through the second imidazole N atom and an ortho-C atom of the adjacent phenyl ring. The structures of [(eta6-p-MeC6H4CHMe2)RuCl2(mtzH)] (1), 2, 4 and 6 were established by X-ray structural analysis.

  DOI：

  10.1016/s0020-1693(00)85114-2