(η5-C5H5)Fe(CO)2(SiMe2)2(η5-C5H5)Fe(CO)2 | 54959-07-8

• 英文名称: (η5-C5H5)Fe(CO)2(SiMe2)2(η5-C5H5)Fe(CO)2
• 英文别名: [(η(5)-C5H5)Fe(CO)2]2(SiMe2)2
• CAS: 54959-07-8
• 化学式: C₁₈H₂₂Fe₂O₄Si₂
• 分子量: 470.235
• InChiKey: UVITWJXIHHJGKY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η5-C5H5)Fe(CO)2(SiMe2)2(η5-C5H5)Fe(CO)2 以 甲苯 为溶剂， 以46%的产率得到cis,trans-{(η5-C5H5)Fe(CO)}2(μ-SiMe2)2
  参考文献：
  名称：

  二硅亚烷基桥接的铁二聚体的光化学转化为亚甲硅烷基桥接的铁二聚体

  摘要：

  Photolysis of FpSiMe2SiMe2Fp (Fp = CpFe(CO)2; Cp = eta-C5H5) in C6D6 afforded, in the early stages of photolysis, a mixture of the geometric isomers [CpFe(CO)]2(mu-CO){mu-SiMe(SiMe3)} and [CpFe(CO)]2-(mu-SiMe2)2 (a small amount). Prolonged photolysis gave cis- and trans-[CpFe(CO)]2(mu-SiMe2)2 almost quantitatively. The structure of a geometric isomer of [CpFe(CO)]2(mu-CO){mu-SiMe(SiMe3)} was determined by X-ray crystallography. Crystal data: C17H22Fe2O3Si2, triclinic in the space group P1BAR, a = 9.555 (3) angstrom, b = 14.031 (3) angstrom, c = 7.986 (2) angstrom, alpha = 91.18 (3)-degrees, beta = 113.56 (3)-degrees, gamma = 101.72 (3)-degrees, V = 955.5 (4) angstrom 3, Z = 2, and R(F(o)) = 0.040 for 3792 reflections with \F(o)\ > 3-sigma-(F(o)).

  DOI：

  10.1021/om00050a030

文献信息

• Pannell, Keith H.; Sharma, Hemant, Organometallics, 1991, vol. 10, # 4, p. 954 - 959
  作者：Pannell, Keith H.、Sharma, Hemant

  DOI：——

  日期：——
• Sharma, Sneh; Cervantes, Jorge; Mata-Mata, Jose Luis, Organometallics, 1995, vol. 14, # 9, p. 4269 - 4274
  作者：Sharma, Sneh、Cervantes, Jorge、Mata-Mata, Jose Luis、Brun, Mari-Carmen、Cervantes-Lee, Francisco、Pannell, Keith H.

  DOI：——

  日期：——
• Pannell, Keith H.; Cervantes, Jorge; Parkanyi, Laszlo, Organometallics, 1990, vol. 9, # 3, p. 859 - 863
  作者：Pannell, Keith H.、Cervantes, Jorge、Parkanyi, Laszlo、Cervantes-Lee, Francisco

  DOI：——

  日期：——