[RuCl(η6-p-cymene)(κ2-C(CH2SeMe)4)][PF6] | 1246290-68-5

• 英文名称: [RuCl(η6-p-cymene)(κ2-C(CH2SeMe)4)][PF6]
• CAS: 1246290-68-5
• 化学式: C₁₉H₃₄ClRuSe₄*F₆P
• 分子量: 859.806
• InChiKey: AJLANQHRFCRYGI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 tetrakis(methylselenomethyl)methane 以 乙醇 为溶剂， 以83%的产率得到[RuCl(η6-p-cymene)(κ2-C(CH2SeMe)4)][PF6]
  参考文献：
  名称：

  Synthesis and properties of monometallic, homo- and heterobimetallic complexes based on {(η6-arene)RuCl}+ and {(η6-arene)OsCl}+ fragments with tetrathioether and tetraselenoether ligands

  摘要：

  The reaction of [Ru(eta(6)-p-cymene)Cl-2](2) with 2.0 mol equivalents of C(CH2SMe)(4), C(CH2SeMe)(4), 1,2,4,5-C6H2(CH2SMe)(4) or 1,2,4,5-C6H2(CH2SeMe)(4) (L-4) and [NH4][PF6] in ethanol solution forms the [RuCl(eta(6)-p-cymene){kappa(2)-L-4}][PF6] complexes. Similar Os(II) complexes are obtained starting with [Os(eta(6)-p-cymene) Cl-2](2). Treatment of [RuCl(eta(6)-p-cymene){kappa(2)-L-4}][PF6] with a further 0.5 mol equivalents of [Ru(eta(6)-pcymene) Cl-2](2) or reaction of [Ru(eta(6)-p-cymene) Cl-2](2) directly with 1.0 mol equivalent of L-4 forms the homobimetalllic [{RuCl(eta(6)-p-cymene)} 2{kappa(2) k'(2)-L-4}][PF6](2). Reaction of [OsCl(eta(6)-p-cymene)-{kappa(2)-C (CH2SeMe)(4)}][PF6] with [Ru(eta(6)-p-cymene) Cl-2](4) or [PtCl2(MeCN)(2)] affords the heterobimetallic [{OsCl(eta(6)p- cymene)}{RuCl(eta(6)-p-cymene)}{kappa(2) k'(2)-C(CH2SeMe)(4)}][PF6](2) and [{OsCl(eta(6)-p-cymene)}{PtCl2}{kappa(2)k'(2)-C (CH2SeMe)(4)}][PF6] respectively. The complexes have been characterised by multinuclear NMR and IR spectroscopy and X-ray crystallography. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.05.010