fac-Re(CO)3Cl(bis-(5,6-diphenyl-[1,2,4]-triazinyl)pyridine) | 1316251-53-2

• 英文名称: fac-Re(CO)3Cl(bis-(5,6-diphenyl-[1,2,4]-triazinyl)pyridine)
• CAS: 1316251-53-2
• 化学式: C₃₃H₂₀ClN₆O₃Re
• 分子量: 770.22
• InChiKey: VNPUVEMEGAABGU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  五羰基氯铼(I) 、 3,3-双(5,6-二苯基-1,2,4-三嗪) 以 甲苯 为溶剂， 以48%的产率得到fac-Re(CO)3Cl(bis-(5,6-diphenyl-[1,2,4]-triazinyl)pyridine)
  参考文献：
  名称：

  Non-innocent ligand reservoirs for reducing or oxidizing equivalents in carbonylrhenium(I) complexes: 1,1′-Bis(diphenylphosphino)ferrocene (dppf) and bis-triazinyl-pyridine (BTP)

  摘要：

  Organometallic complexes of Re(I) with ligands having opposite redox properties have been synthesized and structurally characterized. X-ray crystal structures of the complexes show typical fac-Re-I(CO)(3) coordination to the redox active ligands. Complete electrochemical and spectroelectrochemical studies on the ligands and the metal complexes were performed. The IR-spectroelectrochemical responses were monitored using the fac-Re(CO)(3) unit as a probe. The 15-20 cm(-1) hypsochromic or bathochromic shift of the nu(CO) bands upon reduction or oxidation is attributed to ligand-centered processes. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.005