[cadmium(II)(2-pyridineformamide N(4)-methylthiosemicarbazone)Cl2]*H2O | 454714-25-1

• 英文名称: [cadmium(II)(2-pyridineformamide N(4)-methylthiosemicarbazone)Cl2]*H2O
• CAS: 454714-25-1
• 化学式: C₈H₁₁CdCl₂N₅S*H₂O
• 分子量: 410.606
• InChiKey: WQFUXYRMIKDJHH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  aqueous cadmium chloride 、 (Z)-2-(amino(pyridin-2-yl)methylene)-N-methylhydrazinecarbothioamide 以 乙醇 为溶剂， 以66.3%的产率得到[cadmium(II)(2-pyridineformamide N(4)-methylthiosemicarbazone)Cl2]*H2O
  参考文献：
  名称：

  Structural studies of metal complexes of 2-pyridineformamide N(4)-methylthiosemicarbazone

  摘要：

  Reduction of 2-cyanopyridine by sodium in dry methanol in the presence of N(4)-methylthiosemicarbazide produces 2-pyridineformamide N(4)-methylthiosemicarbazone, HAm4M. In the crystals of [Ni(HAm4M)(2)](ClO4)(2).2H(2)O, [Zn(Am4M)OAc](2) and [Cd(HAm4M)Cl-2].DMSO the major ligand coordinates via its pyridyl nitrogen, imine nitrogen and sulfur atoms, the last of which forms a thione in the neutral ligand HAm4M and a thiolato group in (Am4M)(-). Both the acetato ligands in [Zn(Am4M)OAc](2) are bis-monodentate bridges, which is unique among acetato-bridged binuclear complexes of thiosemicarbazones of this type. As in the complexes of other 2-pyridineformamide thiosemicarbazones, hydrogen bonds play an important role in these compounds. As well as by X-ray diffractometry, the new compounds were characterized by elemental analysis, FAB mass spectrometry and IR spectroscopy; in the case of the nickel(II) complex, by electronic spectroscopy and by molar conductivity and magnetic susceptibility measurements; and in the case of the zinc(II) and cadmium(II) complexes, by NMR spectroscopy (H-1, C-13 and, for Cd(II), Cd-113). (C) 2002 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(02)00835-5