catena-Poly[[(acetonitrile-N)-dichlorocopper(II)]-μ-2,5-dimethylpyrazine-κ2N:N'] | 403648-21-5

• 英文名称: catena-Poly[[(acetonitrile-N)-dichlorocopper(II)]-μ-2,5-dimethylpyrazine-κ2N:N']
• CAS: 403648-21-5
• 化学式: C₈H₁₁Cl₂CuN₃
• 分子量: 283.647
• InChiKey: CKBUEPLEGAFEDY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,5-二甲基吡嗪 、 乙腈 、 copper(l) chloride 以 乙腈 为溶剂， 生成 catena-Poly[[(acetonitrile-N)-dichlorocopper(II)]-μ-2,5-dimethylpyrazine-κ2N:N'] 、 CuCl-2,5-dimethylpyrazine
  参考文献：
  名称：

  catena-Poly[[(acetonitrile-N)dichlorocopper(II)]-μ-2,5-dimethylpyrazine-κ²N:N′]

  摘要：

  In the structure of the title compound, [CuCl2(C2H3N)-(C6H8N2)], each Cu2+ cation is surrounded by two 2,5-dimethylpyrazine ligands, one acetonitrile ligand and two Cl- anions within a distorted tetragonal pyramid. The acetonitrile ligand, which forms the apex of the pyramid, the Cu2+ cation and the Cl- anions are all located in general positions, whereas each of the 2,5-dimethylpyrazine ligands is located about a centre of inversion. The 2,5-dimethylpyrazine ligands connect the Cu2+ cations via mu -N:N' coordination to form chains.

  DOI：

  10.1107/s0108270101015384