| 254733-98-7

• CAS: 254733-98-7
• 化学式: C₅₀H₄₄Cl₂OP₄Pt₂S
• 分子量: 1277.93
• InChiKey: HYCOPGZZYLCXQO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  在 H₂O₂ 、 CH₃ReO₃ 作用下， 以 not given 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  Two Routes to Bis(μ-diphenylphosphino)methane Diplatinum Halides Bridged by Sulfur Monoxide

  摘要：

  The new compounds Pt-2(mu-diphenylphosphinomethane)(2)(mu-SO)X-2, with X = Cl and I, have been prepared and characterized. One route was to use Pt-2(mu-dppm)(2)X-2 to trap the sulfur monoxide Liberated from decomposition of a sultine intermediate formed from the oxidation. of a thioketone sulfoxide with hydrogen peroxide, catalyzed by CH3ReO3 (MTO). The second and preferable route consists of the oxidation of Pt-2(mu-dppm)(2)(mu-S)X-2 With hydrogen peroxide, catalyzed by CH3ReO3 (MTO). The X-ray structural analysis of Pt-2(mu-dppm)(2)(mu-SO)Cl-2 showed that it has an "A-frame" structure in. which the bridge sulfur atom has the geometry of a distorted trigonal bipyramid.

  DOI：

  10.1021/om9905815