(2,6-bis(8-quinolinylthiomethyl) pyridine)bis(trifluoroacetato)disilver | 1318801-45-4

• 英文名称: (2,6-bis(8-quinolinylthiomethyl) pyridine)bis(trifluoroacetato)disilver
• CAS: 1318801-45-4
• 化学式: C₂₉H₁₉Ag₂F₆N₃O₄S₂
• 分子量: 867.346
• InChiKey: MLFUSLMPEJGUSH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,6-bis (8-quinolinylthiomethyl)pyridine 、 silver trifluoroacetate 以 氯仿 、 乙腈 为溶剂， 以67%的产率得到(2,6-bis(8-quinolinylthiomethyl) pyridine)bis(trifluoroacetato)disilver
  参考文献：
  名称：

  Syntheses, crystal structures and antimicrobial activities of thioether ligands containing quinoline and pyridine terminal groups and their transition metal complexes

  摘要：

  Eleven transition metal complexes of three asymmetrical tridentate thioether ligands, 8-((pyridin-2-yl)methylthio) quinoline (TQMP2), 8-((pyridin-3-yl)methylthio) quinoline (TQMP3), 8-((pyridin-4-yl) methylthio) quinoline (TQMP4) and one symmetrical pentadentate ligand 2,6-bis (8-quinolinylthiomethyl) pyridine (DTQMP) were prepared. The structures of all these complexes were identified by means of elemental analysis (EA), infrared spectra (IR) and single-crystal diffraction, providing three different kinds of basic conformations, (1) discrete mononuclear structures, (2) dinuclear rings and (3) 1D polymer chains. The antibacterial, antifungal and pesticide activities of the four ligands and 11 complexes were also studied. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.073