1,2-dibromo-1,2-bis(2,6-bis[bis(trimethylsilyl)methyl]phenyl)-1,2-bis(tetrahydrofuran)-dialuminate(4) | 1373558-86-1

• 英文名称: 1,2-dibromo-1,2-bis(2,6-bis[bis(trimethylsilyl)methyl]phenyl)-1,2-bis(tetrahydrofuran)-dialuminate(4)
• CAS: 1373558-86-1
• 化学式: C₄₈H₉₈Al₂Br₂O₂Si₈
• 分子量: 1145.76
• InChiKey: VHUQPIKVXQNLPU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,2-dibromo-1,2-bis(2,6-bis[bis(trimethylsilyl)methyl]phenyl)-1-tetrahydrofuran-dialuminate(4) 、 1,2-dibromo-1,2-bis(2,6-bis[bis(trimethylsilyl)methyl]phenyl)-1,2-bis(tetrahydrofuran)-dialuminate(4) 以 氘代苯 为溶剂， 生成 1,2-dibromo-1,2-bis(2,6-bis[bis(trimethylsilyl)methyl]phenyl)-dialuminate(4)
  参考文献：
  名称：

  Synthesis, Structure, and Properties of a Stable 1,2-Dibromodialumane(4) Bearing a Bulky Aryl Substituent

  摘要：

  The stable 1,2-dibromodialumane(4) Bbp(Br)Al-Al(Br)Bbp (1; Bbp = 2,6-bis[bis(trimethylsily)methyl]phenyl) was synthesized by the reduction of the corresponding dibromoalumane etherate BbpAlBr(2)center dot OEt2 (2). The structure and properties of 1 have been elucidated on the basis of the analyses of spectroscopic and crystallographic data and are supported by DFT calculations.

  DOI：

  10.1021/om300237q
• 作为产物：
  描述：

  1,2-dibromo-1,2-bis(2,6-bis[bis(trimethylsilyl)methyl]phenyl)-1-tetrahydrofuran-dialuminate(4) 以 氘代苯 、 甲苯 为溶剂， 生成 1,2-dibromo-1,2-bis(2,6-bis[bis(trimethylsilyl)methyl]phenyl)-1,2-bis(tetrahydrofuran)-dialuminate(4)
  参考文献：
  名称：

  Synthesis, Structure, and Properties of a Stable 1,2-Dibromodialumane(4) Bearing a Bulky Aryl Substituent

  摘要：

  The stable 1,2-dibromodialumane(4) Bbp(Br)Al-Al(Br)Bbp (1; Bbp = 2,6-bis[bis(trimethylsily)methyl]phenyl) was synthesized by the reduction of the corresponding dibromoalumane etherate BbpAlBr(2)center dot OEt2 (2). The structure and properties of 1 have been elucidated on the basis of the analyses of spectroscopic and crystallographic data and are supported by DFT calculations.

  DOI：

  10.1021/om300237q