dichloropalladium(II)[[2-(3,5-dimethylpyrazole-1-yl)phenyl]dimethylamine] | 945756-69-4

• 英文名称: dichloropalladium(II)[[2-(3,5-dimethylpyrazole-1-yl)phenyl]dimethylamine]
• CAS: 945756-69-4
• 化学式: C₁₃H₁₇Cl₂N₃Pd
• 分子量: 392.624
• InChiKey: GAXBQQYEUVXVSY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  sodium tetrachloropalladate(II) 、 [2-(3,5-dimethylpyrazol-1-yl)phenyl]dimethylamine 以 甲醇 为溶剂， 以40%的产率得到dichloropalladium(II)[[2-(3,5-dimethylpyrazole-1-yl)phenyl]dimethylamine]
  参考文献：
  名称：

  Square planar mononuclear Pd(II) complexes of substituted 2-(pyrazole-1-yl)phenylamines with a helical twist

  摘要：

  X-ray crystal structure shows that 3,5-dimethyl-1-(2-nitrophenyl)-1H-pyrazole (DNP) belongs to the rare class of helically twisted synthetic organic molecules. Hydrogenation of DNP gives 2-(3,5-dimethylpyrazole-1-yl)phenylamine (L) which on methylation yields [2-(3,5-dimethylpyrazole-1-yl)phenyl]dimethylamine (L'). Two Pd(II) complexes, PdLCl2 (1) and PdL'Cl-2 (2), are synthesized and characterized by NMR. X-ray crystallography reveals that 1 and 2 are unprecedented square planar complexes which possess well discernible helical twists. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.04.013