(2,2':6',2''-terpyridine)(acetylacetonato)ammineruthenium(II) hexafluorophosphate | 1269822-26-5

• 英文名称: (2,2':6',2''-terpyridine)(acetylacetonato)ammineruthenium(II) hexafluorophosphate
• CAS: 1269822-26-5
• 化学式: C₂₀H₂₁N₄O₂Ru*F₆P
• 分子量: 595.447
• InChiKey: JWQRAJKKZQHPGY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (2,2':6',2''-terpyridine)(acetylacetonato)aquaruthenium(II) hexafluorophosphate 、 氨 以 乙醇 、 水 为溶剂， 以34%的产率得到(2,2':6',2''-terpyridine)(acetylacetonato)ammineruthenium(II) hexafluorophosphate
  参考文献：
  名称：

  A new type of electrochemical oxidation of alcohols mediated with a ruthenium–dioxolene–amine complex in neutral water

  摘要：

  Electrochemical oxidation of [Ru-II(terpy)(sq)(NH3)](+) in neutral water (pH 8.0) at +0.8 V (versus SCE) generated [Ru-II(terpy)(q)(NH2 center dot)](2+) and/or [Ru-III(terpy)(sq)(NH2 center dot)](2+) (terpy = 2,2':6',2 ''-terpyridine, sq = 3,5-di-tert-butyl-1,2-semiquinonate, q = 3,5-di-tert-butyl-1,2-benzoquinone), which played roles in hydrogen abstraction and one-electron acceptor in the catalytic oxidation of methanol, ethanol, and 2-propanol affording formaldehyde, acetoaldehyde, and acetone, respectively, under the electrolysis conditions. Crown Copyright (C) 2010 Published by Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.11.013