([η3:η1-N-tert-butyl-2-(4,7-dimethyl[1,4,7]triazanon-1-yl)ethylamide]La(CCPh)(μ-CCPh))2 | 676524-08-6

• 英文名称: ([η3:η1-N-tert-butyl-2-(4,7-dimethyl[1,4,7]triazanon-1-yl)ethylamide]La(CCPh)(μ-CCPh))2
• CAS: 676524-08-6
• 化学式: C₆₀H₈₂La₂N₈
• 分子量: 1193.18
• InChiKey: WULVTGRBXDPAJC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [η3:η1-N-tert-butyl-2-(4,7-dimethyl[1,4,7]triazanon-1-yl)ethylamide]La(CH2SiMe3)2 、 苯乙炔 生成 ([η3:η1-N-tert-butyl-2-(4,7-dimethyl[1,4,7]triazanon-1-yl)ethylamide]La(CCPh)(μ-CCPh))2
  参考文献：
  名称：

  Neutral and Cationic Alkyl and Alkynyl Complexes of Lanthanum:  Synthesis, Stability, and Cis-Selective Linear Alkyne Dimerization

  摘要：

  Neutral triazacyclononane-amide lanthanum dialkyl and dialkynyl complexes were synthesized and structurally characterized. A cationic triazacyclononane-amide lanthanum monoalkyl species was generated and found to be highly active (tof > 100 h(-1)) in the rare cis-selective catalytic linear dimerization of phenylacetylene.

  DOI：

  10.1021/om034403u