mer-RuCl3(NH3)(CO)(DMSO) | 166105-70-0

• 英文名称: mer-RuCl3(NH3)(CO)(DMSO)
• CAS: 166105-70-0
• 化学式: C₃H₉Cl₃NO₂RuS
• 分子量: 330.605
• InChiKey: AQIMNVAFKFXTMO-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  mer,cis-RuCl3(DMSO)2(CO) 、 氨 以 氯仿 为溶剂， 以55%的产率得到mer-RuCl3(NH3)(CO)(DMSO)
  参考文献：
  名称：

  Carbonyl Derivatives of Chloride-Dimethyl Sulfoxide-Ruthenium(III) Complexes: Synthesis, Crystal Structure, and Reactivity of [(DMSO)2H][trans-RuCl4(DMSO-O)(CO)] and mer,cis-RuCl3(DMSO-O)2(CO)

  摘要：

  The synthesis, spectroscopic characterization and crystal structure of [(DMSO)(2)H][trans-RuCl4(DMSO)(CO)] (3) and mer,cis-RuCl3(DMSO)(2)(CO) (4) are reported (DMSO = O-bonded dimethyl sulfoxide). The two complexes are easily synthesized from [(DMSO)(2)H][trans-RuCl4(DMSO)(2)] (1) and mer,trans-RuCl3(DMSO)(2)(DMSO) (2), respectively, upon reaction with carbon monoxide at room temperature and atmospheric pressure. They represent the first examples of Ru(III) chloride-DMSO-carbonyl complexes. Coordination of carbon monoxide induces the S to O linkage isomerization of the DMSO ligand trans to it. [(DMSO)(2)H][trans-RuCl4(DMSO)(CO)]: orthorhombic, space group Pnma, Z = 4, a = 10.564(1) Angstrom, b = 14.620(3) Angstrom, c = 12.312(1) Angstrom. mer,cis-RuCl3(DMSO)(2)(CO): triclinic, space group P1, Z = 4, a = 6.991(9) Angstrom, b = 13.98(1) Angstrom, c = 14.86(2) Angstrom, alpha = 82.76(8)degrees, beta = 85.83(8)degrees, gamma = 75.41(9)degrees. In both 3 and 4 the DMSO ligand trans to CO is weakly bonded and easily replaced by a nitrogen donor ligand such as NH3 or pyridine.

  DOI：

  10.1021/ic00123a003