| 867061-47-0

• CAS: 867061-47-0
• 化学式: C₄₃H₅₃FeO₃P₂Rh
• 分子量: 838.592
• InChiKey: RPXGMCUYDPXYEI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  acetylacetonato(carbonyl)(tricyclohexylphosphine)rhodium(I) 、 rac-2-[(diphenylphosphanyl)methyl]ferrocenecarboxylic acid 以 not given 为溶剂， 生成
  参考文献：
  名称：

  The Chemistry of Phosphanyl‐ferrocenecarboxylic Ligands

  摘要：

  AbstractThe chemistry of ferrocene attracts considerable research interest even more than 50 years after its discovery, being stimulated mainly by applications of ferrocene ligands in catalysis. To the present day, the design of new ferrocene compounds ensued—sometimes by serendipity—the preparation of unprecedented coordination compounds and organometallic materials and, in the case of ferrocene compounds containing appropriate donor sets, led to numerous successful catalytic systems. This review provides a systematic survey of the chemistry of phosphanyl‐ferrocenecarboxylic ligands as a specific class of hybrid ferrocene ligands that emerged about ten years ago, illustrating their synthesis, coordination behaviour, and catalytic applications. Attention is also paid to the structural chemistry of these functional ferrocene ligands. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

  DOI：

  10.1002/ejic.200500485