[Li(N,N,N'N'-tetramethylethylenediamine)2][Mo(η5-C5H5)(CO)3] | 1153574-95-8

• 英文名称: [Li(N,N,N'N'-tetramethylethylenediamine)2][Mo(η5-C5H5)(CO)3]
• CAS: 1153574-95-8
• 化学式: C₈H₅MoO₃*C₁₂H₃₂LiN₄
• 分子量: 484.42
• InChiKey: YOZOXGPUUFXMOV-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  Li{Mo(CO)3(η5-C5H5)} 、 四甲基乙二胺 以 neat (no solvent) 为溶剂， 生成 [Li(N,N,N'N'-tetramethylethylenediamine)2][Mo(η5-C5H5)(CO)3]
  参考文献：
  名称：

  Structural characterization of the anionic halfsandwich complex and its reactivity towards stannanes and distannanes

  摘要：

  The crystal structure of the molybdenum half sandwich alkali salt [Li(TMEDA)(2)][Mo(eta(5)-C5H5)(CO)(3)] shows the occurrence of a separated ion pair in the solid state. Furthermore, the crystal structures of the long known organotin complexes [Mo(eta(5)-C5H5)(SnMe3)(CO)(3)], [{Mo(eta(5)-C5H5)(CO)(3)}(2)SnMe2] and [Mo(eta(5)-C5H5)(SnMeCl2)(CO)(3)] have been recorded. The chlorination of [Mo(eta(5)-C5H5)(SnMe3)(CO)(3)] with SnCl4 is presented as an improved synthetic access to [Mo(eta(5)-C5H5)(SnMeCl2)(CO)(3)]. Finally, the reaction of Li[Mo(eta(5)-C5H5)(CO)(3)]with Bu-t(2)(Cl)Sn-Sn(Cl)Bu-t(2) leads to the novel molybdenum distannane complex [Mo(eta(5)-C5H5){(SnBu2)-Bu-t-Sn(Cl)Bu-t(2)}(CO)(3)], which is fully characterized by NMR, elemental and X-ray analysis. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.10.028