| 753023-40-4

• CAS: 753023-40-4
• 化学式: C₂₅H₃₄MnN₃O₃
• 分子量: 479.501
• InChiKey: RADRNJMSEWVOET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  benzylpentacarbonylmanganese 、 cinnamaldehyde anil 、 叔丁基异氰酸酯 以 further solvent(s) 为溶剂， 以10%的产率得到
  参考文献：
  名称：

  Manganese carbonyl-mediated reactions of azabutadienes with phenylacetylene, methyl acrylate and other unsaturated molecules

  摘要：

  Reaction of PhCH2Mn(CO)(5) with 1,4-di-aryl-1-aza-1,3-butadienes gave substituted pyrrolinonyl rings which Were eta(4)-coordinated to a Mn(CO)(3) group. These are formed by intramolecular CO insertion into a (non-isolated) cyclomanganated intermediate, followed by cyclisation. Other unsaturated reagents (PhC drop CH, CH2 = CHCOOMe, PhNCO) gave products arising from insertion of these, including a structurally characterised tri-aryl-eta(5)-azacyclohexadienyl-Mn(CO)(3) complex from the reaction with the alkyne. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.04.042