| 851520-16-6

• CAS: 851520-16-6
• 化学式: C₃₆H₃₃ClCuN₂PS₃
• 分子量: 719.842
• InChiKey: GUUZPYIENSQCDU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氯化三(三苯基膦)铜(I) 、 2,5,8-trithia[9](2,9)-1,10-phenanthrolinophane 以 乙醇 、 二氯甲烷 为溶剂， 以22.4%的产率得到
  参考文献：
  名称：

  Complexes of CuII with mixed-donor phenanthroline-containing macrocycles: analysis of their structural, redox and spectral properties in the context of Type-1 blue copper proteins biomimetic models

  摘要：

  The macrocycles L-1-L-3 having N2S2O-, N2S2-, and N2S3-donor sets, respectively, and incorporating the 1,10-phenanthroline unit interact in EtOH and MeCN solutions with Cu-II to give 1:1 [M(L)](2+) complex species. The compounds [Cu(L-1)(ClO4)]ClO4 (1), [Cu(L-2)(ClO4)]ClO4 center dot 1/2H(2)O (2) and [Cu(L-3)](ClO4)(2) (3) were isolated at the solid state and the first two also characterised by X-ray diffraction studies. The conformation adopted by L-1 and L 2 in the cation complexes reveals the aliphatic portion of the rings folded over the plane containing the heteroaromatic moiety with the ligands encapsulating the metal centre within their cavity by imposing. respectively, a square-based pyramidal and a square planar geometry. In both complexes, the metal ion completes its coordination sphere by interacting with a ClO4- ligand. The compound [Cu(L-3)(2)](PF6)(2) (4) containing a 1:2 cation complex was also isolated at the solid state: EPR spectroscopy measurements suggest the presence of a CuN4 chromophore in this complex. The EPR and electronic spectral features of 1-4 have been studied and their redox properties examined in comparison with those observed for Type-1 blue copper proteins.The reactivity of L-1-L-3 has also been tested toward stoichiometric amounts of the Cut salt [CuCl(PPh3)(3)], (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.01.014