[(N-methyl-[bis(2-pyridyl)methyl]amine)CuCl(ClO4)]2 | 942593-22-8

• 英文名称: [(N-methyl-[bis(2-pyridyl)methyl]amine)CuCl(ClO4)]2
• 英文别名: [(Me-bpa)CuCl(ClO4)2]
• CAS: 942593-22-8
• 化学式: C₂₆H₃₀Cl₄Cu₂N₆O₈
• 分子量: 823.464
• InChiKey: BIRBAAVWDFVXTP-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper dichloride 、 N-methyl-N,N-bis(2-pyridylmethyl)amine dihydroperchlorate 以 甲醇 为溶剂， 以43%的产率得到[(N-methyl-[bis(2-pyridyl)methyl]amine)CuCl(ClO4)]2
  参考文献：
  名称：

  Isomerism in copper(II) chloride complexes of bis(2-pyridylmethyl)amine and N-substituted derivatives: Synthesis and X-ray structural characterisation

  摘要：

  Copper(II) chloride complexes of tridentate N-alkylated bis(2-pyridylmethyl)amine ligands (R-bpa) form coordination oligomers with either terminal or bridging chloride. Two structural types are identified by X-ray diffraction: a mono p-chloro bridged species and a di-mu-chloro bridged species, both containing five-coordinate copper(II). In each case, the c parameter indicates only small deviations from regular square-pyramidal coordination geometry. The product structure is dependent on the presence or absence of non-coordinating anions. In the presence of C10(4)(-) or PF6-, cationic dinuclear complexes are formed, driven by the formation of an ionic lattice. In the absence of non-coordinating anions, neutral mononuclear [CuCl2(R-bpa)] complexes are formed. Chloride concentration in methanol solution exerts less influence on the reaction outcome, despite differing chloride stoichiometries in the isolated products. In the presence of the coordinating acetate anion, cationic products are formed in which the terminal chloride ligands are completely or partially substituted by acetate. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.12.005

文献信息

• Syntheses, characterization, and reactivity of copper complexes with tridentate N-donor ligands
  作者：Jörg Astner、Markus Weitzer、Simon P. Foxon、Siegfried Schindler、Frank W. Heinemann、Jhumpa Mukherjee、Rajeev Gupta、Viswanath Mahadevan、Rabindranath Mukherjee

  DOI：10.1016/j.ica.2007.07.018

  日期：2008.1

  The reaction of dioxygen with the copper(I) complex of the tridentate ligand 1,1,4,7,7-pentamethyldiethylenetriamine (Me(5)dien) has been investigated using low-temperature stopped-flow techniques. The formation of a bis( mu-oxo)copper(III) complex as a reactive intermediate could be detected spectroscopically at low temperatures and a quantitative kinetic analysis was performed for this system. Crystal structures of the copper(II) complexes [(Me-bpa)Cu(Cl)(2)] (1), [(Me-bpa)Cu(Cl)(ClO4)}(2)] (2), [(MeL)Cu(Cl)(ClO4)}(2)] (3), and [(MeL)Cu(NCS)(2)] (4) (Me-bpa=N-methyl-[bis(2-pyridyl)methyl]amine; MeL=N-methyl-[(2-pyridyl)ethyl(2-pyridyl)methyl]amine) are reported. (c) 2007 Elsevier B.V. All rights reserved.