ZnCl2(bis(1-methylthioimidazolyl)methane) | 1265708-29-9

• 英文名称: ZnCl2(bis(1-methylthioimidazolyl)methane)
• CAS: 1265708-29-9
• 化学式: C₉H₁₂Cl₂N₄S₂Zn
• 分子量: 376.649
• InChiKey: HYEARXPAMYNFNA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(1-methyl-1H-imidazol-2-ylthio)methane 、 zinc(II) chloride 以 甲醇 、 二氯甲烷 为溶剂， 以72%的产率得到ZnCl2(bis(1-methylthioimidazolyl)methane)
  参考文献：
  名称：

  A comparison of the coordination of two linkage isomers of bis(1-methylthioimidazolyl)methane to zinc salts

  摘要：

  A structural comparison of the coordination chemistry of the two linkage isomeric forms of bis(1-methylthioimidazolyl)methane, [H2C(N-mt)(2)] (L-S), and [H2C(S-mt)(2)] (L-N) to a number of zinc complexes has been carried out. The complexes ZnX2LS and ZnX2LN (where X = Cl, Br and I) have all been prepared in good to high yields and have been characterised by spectroscopic and analytical methods. X-ray crystallography studies were also carried out on all of the newly prepared compounds, revealing kappa(2)-SS and kappa(2)-NN coordination modes for L-S and L-N containing complexes, respectively. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.08.027