[NBu4][Ni(C6F5)2(S(S)P(C5H4FeC5H5)(OMe))] | 691873-55-9

• 英文名称: [NBu4][Ni(C6F5)2(S(S)P(C5H4FeC5H5)(OMe))]
• CAS: 691873-55-9
• 化学式: C₁₆H₃₆N*C₂₃H₁₂F₁₀FeNiOPS₂
• 分子量: 946.443
• InChiKey: WNIHYAHWMFXGAD-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  、 (NBu4)2{(C6F5)2Ni(μ-OH)2Ni(C6F5)2} 以 二氯甲烷 为溶剂， 以62%的产率得到[NBu4][Ni(C6F5)2(S(S)P(C5H4FeC5H5)(OMe))]
  参考文献：
  名称：

  Organometallic nickel(II) complexes with dithiophosphate, dithiophosphonate and monothiophosphonate ligands

  摘要：

  The hydroxo complex [NBu4](2)[Ni-2(C6F5)(4)(mu-OH)(2)] reacts with ammonium O, O'-dialkyldithiophosphates, O-alkyl-p-methoxyphenyldithiophosphonate acids and ammonium O-alkylferrocenyldithiophosphonates in dichloromethane under mild conditions to give, respectively, [NBu4][Ni(C6F5)(2){S(S)P(OR)(2)}] (R=Me (1), Et (2), Pr-i (3)) and [NBu4][Ni(C6F5)(2){S(S)P(OR)Ar}] (Ar=p-MeOC6H4, R = Me (4), Et (5), Pr-i (6); Ar = ferrocenyl; R = Me (7), Et (8), Pr-i (9)). The monothiophosphonate nickel complexes [NBu4][Ni(C6F5)(2) {S(S)P(OR)(ferrocenyl))] (R=Et (10), Pr-i (11)) are obtained by reaction of the hydroxo complex with O-alkylferrocenyldithiophosphonate acids. Analytical (C, H, N, S), conductivity, and spectroscopic (IR, H-1, F-19 and P-31 NMR, and FAB-MS) data were used for structural assignments. A single-crystal X-ray diffraction study of [NBu4][Ni(C6F5)(2){S(S)P(OMe)(p-MeOC6H4)}] (4) and [NBu4][Ni(C6F5)(2){S(O)P(OEt)(ferrocenyl)}] (10) shows that in both cases the coordination around the nickel atom es essentially square planar with NiC2S2 and NiC2SO central cores, respectively. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.06.013